Investigation of the modifier 2-benzofuran-1,3-dione content effect on the heat resistance of epoxy composites
| Назва | Investigation of the modifier 2-benzofuran-1,3-dione content effect on the heat resistance of epoxy composites |
| Назва англійською | Investigation of the modifier 2-benzofuran-1,3-dione content effect on the heat resistance of epoxy composites |
| Автори | Oleksandr Sapronov, Vitalii Sotsenko, Anna Sapronova, Pavlo Vorobiov, Mykola Brailo, Vitalii Yatsuk |
| Принадлежність | Kherson State Maritime Academy, Kherson, Ukraine Ternopil Research Forensic Center of MIA of Ukraine, Ternopil, Ukraine |
| Бібліографічний опис | Investigation of the modifier 2-benzofuran-1,3-dione content effect on the heat resistance of epoxy composites / Oleksandr Sapronov, Vitalii Sotsenko, Anna Sapronova, Pavlo Vorobiov, Mykola Brailo, Vitalii Yatsuk // Scientific Journal of TNTU. — Tern.: TNTU, 2022. — Vol 105. — No 1. — P. 55–67. |
| Bibliographic description: | Sapronov O., Sotsenko V., Sapronova A., Vorobiov P., Brailo M., Yatsuk V. (2022) Investigation of the modifier 2-benzofuran-1,3-dione content effect on the heat resistance of epoxy composites. Scientific Journal of TNTU (Tern.), vol 105, no 1, pp. 55–67. |
| DOI: | https://doi.org/10.33108/visnyk_tntu2022.01.055 |
| УДК | 667.64:678.026 |
| Ключові слова | epoxy binder, modifier, hardener, heat resistance, destruction, activation energy. |
The technological aspects of modification of epoxy oligomer DER – 331 to provide improvement of thermophysical characteristics of composite materials and protective coatings based on them are presented. Cold-cured triethylenetetramine TETA hardener was used to crosslink the epoxy binder (q = 10 parts by weight per 100 parts by weight of DER-331 epoxy resin). Thermogravimetric (TGA) and differential thermal (DTA) analysis was performed to study modified composites under the influence of elevated temperatures. A mathematical calculation of the values of the activation energy of thermal destruction to determine the resistance to destruction of chemical bonds under the influence of temperature factor. | |
| ISSN: | 2522-4433 |
| Перелік літератури |
1. Suberlyak O. V., Krasinskyi V. V., Shapoval Y. M., Grytsenko O. M. Influence of the mechanism and parameters of hardening of modified novolac phenol-formaldehyde resins on the physicomechanical properties of the composite. Materials Science. 2011. Vol. 46. Issue 5. P. 669–678.
2. Buketov А. V., Sapronov О. О., Brailo М. V. Investigation of the Physico-Mechanical and Thermophysical Properties of Epoxy Composites with a Two-Component Bidisperse Filler. Strength of Materials. 2014. Vol. 46. No. 5. P. 717–723.
3. Buketov A., Maruschak P., Sapronov O., Brailo M., Leshchenko O., Bencheikh L., Menou A. Investigation of thermophysical properties of epoxy Nanocomposites. Molecular Crystals and Liquid Crystals. 2016. Vol. 628. P. 167–179.
4. Lysenkov Е. A. and Klepko V. V. Characteristic features of the thermophysical properties of a system based on polyethylene oxide and carbon nanotubes. Journal of Engineering Physics and Thermophysics. 2015. Vol. 88. No. 4. P. 1008–1014.
5. Ben A., Sapronov O., Buketova N., Yatsiuk V. Doslidzhennia vplyvu modyfikatora 3,31 – (1,4 – fenilen) bis (2 – khloropropionitrylu) na vlastyvosti epoksydnoi matrytsi. Fizyko-khimichna mekhanika materialiv. 2014. Vol. 10. P. 341–346.
6. Savchuk P. P., Kostornov A. G., Kashitskii V. P., Sadova O. L. Friction Wear of Modified Epoxy Composites. Powder Metallurgy and Metal Ceramics. 2014. Volume 53. Issue 3–4. P. 205–209.
7. Buketov A. V., Sapronov A.A., Yatsiuk V. N., Hryshchuk B. D., Baranovskyi V.S. Yssledovanye vlyianyia 1,4 – bys (N,N dymetyldytyokarbamato) benzena na mekhanycheskye svoistva epoksydnoi matryts. Plastycheskye massi. 2014. No. 3–4. P. 26–34.
8. Buketov A. V., Braylo N. V., Sapronov O. O., Yatsiuk V. N., Akymov A. V. Yssledovanye vlyianyia modyfykatora 2 – metyl – 2 – tyotsyanato – 3 – (4 – tyotsyanatofenyl) propyoamyda na strukturu y svoistva epoksydnoi matrytsi. Mekhanyka kompozytsyonnikh materyalov y konstruktsyi. 2014. No. 4 (20). P. 539–554 9. Akimov A. V., Buketov A. V., Sapronov О. О., Brailo M. V., Yakushchenko S. V., Smetankin S. A. Development of polymer composites with improved thermophysical properties for shipbuilding and ship repair. Composites: Mechanics, Computations, Applications: An International Journal. 2019. Vol. 10. No. 2. P. 117–134.
10. Dinzhos R. V., Fialko N. M., Lysenkov E. A. Analysis of the Thermal Conductivity of Polymer Nanocomposites Filled with Carbon Nanotubes and Carbon Black. J. of Nano- Electron. Phys. 2014. Vol. 6. No. 1. Р. 01015-1– 01015-6. 11. Misyura A. I., Mamunya Ye. P. Elektroprovidnist` ta teploprovidnist` metalopolimerny`x kompozy`tiv. Metallofy`zy`ka y` novejshy`e texnology`y`. 2018. T. 40. No. 3. Р. 311–326. 12. Sapronov O. O., Buketov A. V., Yakushchenko S. V., Syzonenko O. M., Sapronova A. V., Sotsenko V. V, Vorobiov P. O., Lypian Ye. V., Sieliverstov I. A., Dobrotvor I. H. Application of synthesized iron/titanium carbide mixture for restoration of water transport parts by epoxy composites. Composites: Mechanics, Computations, Applications: An International Journal. 2021. Vol. 12 (4). P. 23–35.
13. Buketov A. V., Smetankin S. А., Akimov А. V., Kulinich А. G. Epoxy composite modifications influence on the energy activation’s of thermal destruction. Funct. Mater. 2019. Vol. 26. No. 2. P. 403–411.
14. Buketov A. V., Kulinich A. G., Akimov A. V., Smetankin S. A., Gusev V. N., Levkivskyi R. N. Research of Activation Energy of Thermal Breakdown of Polymer Composites Modified By 4-Aminobenzoic Acid. Composites: Mechanics, Computations, Applications: An International Journal. 2020. Vol. 11. No. 2. P. 99–112.
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| References: |
1. Suberlyak O. V., Krasinskyi V. V., Shapoval Y. M., Grytsenko O. M. Influence of the mechanism and parameters of hardening of modified novolac phenol-formaldehyde resins on the physicomechanical properties of the composite. Materials Science. 2011. Vol. 46. Issue 5. P. 669–678.
2. Buketov А. V., Sapronov О. О., Brailo М. V. Investigation of the Physico-Mechanical and Thermophysical Properties of Epoxy Composites with a Two-Component Bidisperse Filler. Strength of Materials. 2014. Vol. 46. No. 5. P. 717–723.
3. Buketov A., Maruschak P., Sapronov O., Brailo M., Leshchenko O., Bencheikh L., Menou A. Investigation of thermophysical properties of epoxy Nanocomposites. Molecular Crystals and Liquid Crystals. 2016. Vol. 628. P. 167–179.
4. Lysenkov Е. A. and Klepko V. V. Characteristic features of the thermophysical properties of a system based on polyethylene oxide and carbon nanotubes. Journal of Engineering Physics and Thermophysics. 2015. Vol. 88. No. 4. P. 1008–1014.
5. Ben A., Sapronov O., Buketova N., Yatsiuk V. Doslidzhennia vplyvu modyfikatora 3,31 – (1,4 – fenilen) bis (2 – khloropropionitrylu) na vlastyvosti epoksydnoi matrytsi. Fizyko-khimichna mekhanika materialiv. 2014. Vol. 10. P. 341–346.
6. Savchuk P. P., Kostornov A. G., Kashitskii V. P., Sadova O. L. Friction Wear of Modified Epoxy Composites. Powder Metallurgy and Metal Ceramics. 2014. Volume 53. Issue 3–4. P. 205–209.
7. Buketov A. V., Sapronov A.A., Yatsiuk V. N., Hryshchuk B. D., Baranovskyi V.S. Yssledovanye vlyianyia 1,4 – bys (N,N dymetyldytyokarbamato) benzena na mekhanycheskye svoistva epoksydnoi matryts. Plastycheskye massi. 2014. No. 3–4. P. 26–34.
8. Buketov A. V., Braylo N. V., Sapronov O. O., Yatsiuk V. N., Akymov A. V. Yssledovanye vlyianyia modyfykatora 2 – metyl – 2 – tyotsyanato – 3 – (4 – tyotsyanatofenyl) propyoamyda na strukturu y svoistva epoksydnoi matrytsi. Mekhanyka kompozytsyonnikh materyalov y konstruktsyi. 2014. No. 4 (20). P. 539–554 9. Akimov A. V., Buketov A. V., Sapronov О. О., Brailo M. V., Yakushchenko S. V., Smetankin S. A. Development of polymer composites with improved thermophysical properties for shipbuilding and ship repair. Composites: Mechanics, Computations, Applications: An International Journal. 2019. Vol. 10. No. 2. P. 117–134.
10. Dinzhos R. V., Fialko N. M., Lysenkov E. A. Analysis of the Thermal Conductivity of Polymer Nanocomposites Filled with Carbon Nanotubes and Carbon Black. J. of Nano- Electron. Phys. 2014. Vol. 6. No. 1. Р. 01015-1– 01015-6. 11. Misyura A. I., Mamunya Ye. P. Elektroprovidnist` ta teploprovidnist` metalopolimerny`x kompozy`tiv. Metallofy`zy`ka y` novejshy`e texnology`y`. 2018. T. 40. No. 3. Р. 311–326. 12. Sapronov O. O., Buketov A. V., Yakushchenko S. V., Syzonenko O. M., Sapronova A. V., Sotsenko V. V, Vorobiov P. O., Lypian Ye. V., Sieliverstov I. A., Dobrotvor I. H. Application of synthesized iron/titanium carbide mixture for restoration of water transport parts by epoxy composites. Composites: Mechanics, Computations, Applications: An International Journal. 2021. Vol. 12 (4). P. 23–35.
13. Buketov A. V., Smetankin S. А., Akimov А. V., Kulinich А. G. Epoxy composite modifications influence on the energy activation’s of thermal destruction. Funct. Mater. 2019. Vol. 26. No. 2. P. 403–411.
14. Buketov A. V., Kulinich A. G., Akimov A. V., Smetankin S. A., Gusev V. N., Levkivskyi R. N. Research of Activation Energy of Thermal Breakdown of Polymer Composites Modified By 4-Aminobenzoic Acid. Composites: Mechanics, Computations, Applications: An International Journal. 2020. Vol. 11. No. 2. P. 99–112.
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